Both k3b and k9copy have config settings that point to the optical drive(s). You should check these. I think the optical devices are something like /dev/sr0, /dev/sr1. Sometimes there are aliases to these devices like cdrom1, dvd1, and so on. Look in your /dev dir to see. As way to check try this cmd:
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$ eject /dev/sr0
this should open the drive in question. Once you have the correct device name, make sure k3b and k9copy settings have these. Hope this helps.