Second - can you ping an IP?
Like
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ping -c 2 74.125.39.103
If you can try this
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ping -c 2 74.125.39.103
What? I had to google pppoe and it seems that it can be used by a LAN but I have not heard of that beforethe pppoe connection is made over a lan .
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gksu gedit /etc/network/interfaces